Using the mount command

What does it take to use the mount command to auto-mount a home NAS with a windows-samba share and make it look to the OS like local storage?

Does this require dev mode, Crouton or such like or can it be done out of the box?

I want to be able to play a music library held on the NAS as if it's been downloaded from Google Play Music. Note, I'm not interested in uploading it all to Google Music, or accessing a media server running on the NAS, or using the web access on the NAS.